| | Position | Player | WCs | Played | Min | Goals | WC Wins |
| Starting XI | | | | | | | |
| 1 | G | Iker Casillas | 3 | 15 | 1440 | 0 | 1 |
| 2 | RB | Sergio Ramos | 2 | 10 | 917 | 0 | 1 |
| 12 | CB | Andoni Goikoetxea | 1 | 4 | 360 | 1 | 0 |
| 6 | CB | Carles Puyol | 3 | 14 | 1344 | 1 | 1 |
| 3 | LB | José Antonio Camacho | 2 | 10 | 930 | 0 | 0 |
| 19 | MF | Fernando Hierro | 4 | 12 | 1017 | 5 | 0 |
| 4 | MF | Xavi | 3 | 14 | 1034 | 0 | 1 |
| 8 | MF | Andrés Iniesta | 2 | 7 | 647 | 1 | 1 |
| 13 | MF | Estanislao Basora | 1 | 6 | 540 | 4 | 0 |
| 11 | ST | David Villa | 2 | 11 | 846 | 7 | 1 |
| 7 | ST | Fernando Morientes | 2 | 7 | 465 | 5 | 0 |
| Squad | | | | | | | |
| 22 | G | Andoni Zubizarreta | 4 | 16 | 1500 | 0 | 0 |
| 16 | RB | Albert Ferrer | 2 | 6 | 495 | 0 | 0 |
| 5 | CB | Gerard Piqué | 1 | 7 | 660 | 0 | 1 |
| 15 | CB | Miguel Ángel Nadal | 3 | 9 | 762 | 0 | 0 |
| 20 | LB | Joan Capdevila | 1 | 7 | 660 | 0 | 1 |
| 14 | MF | Xabi Alonso | 2 | 10 | 828 | 1 | 1 |
| 17 | MF | Míchel | 2 | 9 | 836 | 4 | 0 |
| 21 | MF | Luis Enrique | 3 | 12 | 896 | 2 | 0 |
| 10 | ST | Raúl | 3 | 11 | 716 | 5 | 0 |
| 18 | ST | Julio Salinas | 3 | 12 | 957 | 3 | 0 |
| 9 | ST | Emilio Butragueño | 2 | 9 | 762 | 5 | 0 |
| Squad | | | 51 | 218 | 18612 | 44 | 9 |
| Starting XI | | | 25 | 110 | 9540 | 24 | 6 |
